From the Aluminum Extruders Council (AEC) FAQ's:
"
I'm in the market for some extruded aluminum heat sinks. Which alloy is best for this type of application? The purpose of any heat sink material is the dissipation of heat. Although all aluminum is capable of this, the specific alloy 6063 works best, when all aspects of aluminum in this application are considered. This alloy finishes well, and is machinable to most user needs. It's one of the most cost-effective alloys for this purpose. This alloy's characteristics lend themselves well to the sharp corners and tight spaces of some heat sink designs.
Can an extrusion provide enough heat dissipation to cool my electrical components? With only copper, silver and gold having better thermal conductivity, aluminum historically provides the most cost-effective solution while the extrusion can be designed to allow the maximum cooling area where it's most needed. Designing in serrated surfaces greatly increases the cooling area."
The USA tends to use the slightly stronger Al 6061-T6 rather than 6063.
A Google search suggests that China mostly uses anodized Al 6060, 6061, 6063 and K7 for heat sinks.
From
Aluminum, Vol. II, Design and Application, pages 551-2 & 555 (1967):
"The extrudability of aluminum permits...Configurations ideal for heat dissipation can be produced economically (Fig. 12). Extruded aluminum, usually of 6xxx series alloys, can be color anodized to increase the emissivity of the radiating surfaces..."
From 'Extrusion of AlMgSi Alloys,' O. Reiso,
MATERIALS FORUM VOL.28, pages 32-46 (2004):
"The amounts of the different alloys used for extrusion purposes are shown in Figure 2 [2].
* Clearly the dominating alloy system for extrusion of aluminium is the 6000 alloy system, i.e. AlMgSi alloys. More than 90% of the total extruded volume is estimated to be made from this alloy system." [for Western Europe, 2000]
*Reference [2] is a Hydro Aluminum document.
Heat Sink Selection, Thermal Management of Electronics, (PowerPoint presentation) San José State University,
"Al alloys used [for casting] have lower conductivity than Al alloys used for extrusions"
'Aluminum (6063 or 6061) is most common..."
"Ideal conditions mean:...The heat sink is painted or anodized black....Thermal interface resistance minimized using grease or pad and by making surfaces as flat as possible"
Some reference on heat sink design (optimization) are given in the final slide.
Also, NASA uses black anodized Al for radiators in space, sometimes even grit-blasted (pre-anodize) for greater surface area. Anodize (clear, gold & black) is mostly used for the International Space Station truss structure, since its IR emissivity keeps it from heating and expanding as much as bare Al in sunlight.