Who do you think we are, The Amazing Kreskin? At best, we can guess at the possibilities. These may be educated guesses, but you can do some forensic investigation with the valve itself and probably know what the issue is. My guess is a valve stem leak, the dowtherm vapors condensed and gummed up the valve stem, and it got stuck. My advice is seek the help of a knowledgeable instrument mechanic and go look into it with them.
Good luck,
Latexman
To a ChE, the glass is always full - 1/2 air and 1/2 water.