"Both the Generator (13.8kV, 160MVA) and Step-up Transformer (13.8/115kV, 166MVA) have their dedicated differential protection. "
I see this as added protection as back up to the primary units. If you can live with lower sensitivity if it is a back up unit (high slope / second slope) settings most modern relays will satisfy your initial requirements. You will want to also pay attention to the CT's for matching performance and lead length / burden issues for a run that long. What you don't want is your back up protection to nuisance trip for a through fault, due to saturation issues. On a 160 MVA unit that could be quite a distance between the Gen Neutral CTs and the Transformer HV side or HV breaker, if you choose to further extend the back up protection to cover the breaker.