Your question is quite vauge, but here goes
Fracture toughness will depend on quite a few variables, including how you induce the fracture.
Most plastics data shows energy at break by a pendulum swinging against a sample held in a vice. Most real world fractures occur by a very different mode, which is more realistically represented by dropped dart tests or elongation at break figures.
For the same plastic including the same grade, and real world failures, the biggest accross the board variable is notches in the design. Compared to metals, plastics are very notch sensitive. Various plastics have varying degree of notch sensitivity.
There are several other important variables that only apply to some types of plastic. These are:-
Degree of crystalinity.
Type of crystals.
Size of crystals.
Environmental stress cracking.
Fatigue.
Exposure to UV light.
Long term effects of exposure to heat and air.
Moisture conditioning.
Skin layer effects.
Moulded in stress.
Anealing.
Changes in section thickness.
molecular orientation vs load (dependant on flow direction while moulding)
Reinforcing fibre orientation (if present).
Factors dependant on grade of polymer used are:-
Molecular weight.
Plasticisers.
Impact modifiers.
Fillers and reinforcements.
Other additives such as flame retardants.
Colours.
Alloys.
Neucleating agents.
Lubricants.
Chemical type of polymer.
Degree and type of cross linke if any.
Molecular weight distribution, including pressence of very low molecular weight components
Factors depending on test conditions:-
Temperature at which tests done.
Thickness of sample.
Cut or moulded notch.
High speed low weight or low speed high weight impact.
That's all I can do now of the top of the head.
If you have more questions can you please be much more specific
Regards
pat
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