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Fluorine Compounds ans Stainless Steel

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MOB1

Materials
Feb 11, 2003
69
Does anyone have references which detail the problems of austenitic stainless steels and fluorine compounds?
I have an aluminum smelter client who was attempting to change from carbon steel to austenitic stainless for a gas scrubber from the anode bake ovens. The gas contains all sorts of nasties like HF (and other fluoride compounds), SO2, NOx, CO2 and is at a temperature of minimum 150C.
My immediate thoughts were internal Stress corrosion cracking and general corrosion with the possibility of external stress corrosion cracking under insulation.
I have to prove that the combination of flouride compounds would probably cause stress coorrosion cracking internally.
By the way, the original carbon steel scrubber was 25 years old.
 
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I have references for low levels of F that show it acts like Cl, or a little worse. I have no data in high concentrations of F salts. Now I am going to have to look around.
Off hand I like your gut feel, go back with CS. In fact if you find a grade with just a little bit of Cr you may even do better.

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