Correct me if I'm wrong everybody. Storm sewers are sized for the peak rate of a given storm frequency. Like I said, the storm sewers in my area can be designed for the 10 yr storm (Rational), but the backbone system needs to be designed to the 25 yr storm (routing with SCS). I think the reasoning is that the 10 yr designed pipes can handle a 25 yr storm except for a few hours at the peak (and by this point the roadway is flooded or almost flooded anyhow, so what's the difference).
Also, I don't know the exact reason behind it, but I've been told that the Rational Formula produces higher runoff values say SCS, etc.