TD2K's idea of evaluating the design temp is a good one.
Presumably the instrumentation is B31.3. If so you could invoke the 90% design temp rule in 301.3.2(b)(2) which states (read the Code yourself for exceptions!) that the design temp for uninsulated flanges may be taken as 90% of the fluid, or 153°F. Not quite the 145°F you're looking for, but much closer. Now verify that you meet 302.2.4 (especially the "owners approval" part!) and you're probably home free.
If you can upgrade to a 321 material (Group 2.4) then the 90% design temp rule gets you there (1363 psi at 153°F) without going to 302.2.4. I still recommend getting the owners approval on this approach.
Another option for you to consider may be to upgrade the flange to a 347 flavor (Group 2.5) which, if I did my interpolation correctly, has a DP of 1359 psi.
jt