A flameproof EEx "d" motor suitable for Class I, Zone 0 must not permit ESCAPE to the outside atmosphere of any flame or hot gas that could ignite the surrounding atmosphere.
Painting over the whole motor enclosure of any color will not restrict to pass ATEX inspection. No industry codes and standards that will restrict you to use any color of the paint.
The ambient air of the atmosphere will affect the temperature classification of the motor, NOT the paint.
Regards,
Bilegan
Murphy's Law - If anything can go wrong..it will.