Bubble formation is influenced by the wetting properties of the liquid and the finish of the surface. To avoid the insulating effect that vapour bubbles have, a wetting agent is added to certain liquids, such as magnesium in mercury boilers.
Bubbles start at specific sites. A rough surface will have more sites where bubbles can start than a polished surface, and therefore has a higher coefficient of heat transfer.
This is one reason for using evaporators with finned surfaces for simple clean liquids that do not scale up, as the refrigerants R11 and R115.
In most cases however, smooth surfaces are preferred, to reduce the risk of scale formation and to make cleaning easier. Evaporators for spent sulphite liquor have polished surfaces.
The HTC rises with increasing temperature differences up to a maximum value, h
max, at a "critical" temperature difference, and decreases at higher temperature differences. The increase is due to the greater number of bubbles giving more interface between bubbles and liquid, and the increased agitation from the rising bubbles. This is called 'pool' boiling.
The insulating or blanketing effects of the bubbles at the HT surface at higher temperature differences has already been explained by PlantEng and rmw.
The critical temperature difference for film boiling is a function of the "reduced" pressure p
r of the boiling fluid, namely the ratio of the prevailing pressure to the critical pressure, p
c of the boiling compound.
Designs of industrial evaporators aim at tep. differences well below the critical temperature difference to avoid film boiling.
Graphs show that the critical temperature difference for film boiling increases with lower reduced pressures.
Some examples. For acetone boiling at atmospheric pressure (p
r=0.021) the value for the critical temp. difference would be around 69
oF. For pentane (p
r=0.03): 63
oF. For ethanol boiling at atmospheric pressure (p
r=0.0157), the difference would be 76
oF. For water (p
r=0.0045) it would be about 115
oF. Water boiling at 22.1 atmospheres (p
r=0.1) the crit. temp. difference would drop to 47
oF. These data were worked out from Chilli and Bonilla: "Heat transfer to liquids boiling under pressure"
Trans.A.I.Ch.E.,
41, No.6, 755 (1945).
Although to my knowledge there is still no general equation for estimating the HTC for all boiling liquids there are some for pure compounds boiling over horizontal tubes. Even these give only ballpark estimates, or orders of magnitude.
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