Ah yes Scotty, I too love the smell of burning silicon in the mornings !
I have been in and out of the power electronics game for many years. The highest powered switchers I had to design were for charging the pulse forming network of a pulsed solid state laser in the megawatt range. It was all hush hush for the government, so cannot say much about it.
Another rather interesting application for a very high voltage, high power switching power supply actually used a radio transmitting valve, believe it or not.
Later, I was designing really small switching supplies for telecommunications equipment. Another interesting job was designing fairly large no break computer supplies that used ferro-resonant transformers. All interesting stuff.
I have to agree with you, in that what at first looks rather simple, can quickly turn out not to be, and there is no substitute for experience. The only way to get that is the hard way, unfortunately.