In my opinion and experience (and now for the "con" side to pacometers)...
One possible drawback to a magnetic scanner, pacometer, whatever you wish to call it, on a masonry wall could be that while you may be able to pick up the reinforcing, you may very well pick up on the wire reinforcing placed between the CMU blocks embedded in the mortar, which may give you a false reading.
Also, reinforcing at door locations and wall joints are usually doubled up, but the scanner will only accurately pick up that reinforcing is there, not how much reinforcing...if it doesn't pick up on the door jamb.
Short of mini-drilled holes spaced at a certain preset on center (32" or 48", usually), other methods could be considered a best-guess scenario.