The PV value is not directly related to the usual mechanical properties reported for a material, and as has been noted, the units are different.
The V part is a velocity, of course.
The P part is a pressure computed on the projected area of the bearing, and the allowable pressure is usually orders of magnitude lower than the compressive yield stress.
What happens to a given bearing material at PV values above the limit depends to a large extent on whether the P is excessive or the V is excessive. I.e., the resulting failure modes are usually different for each bearing material, and they are different from one bearing material to another.
That said, the usual result of excessive V is, as noted, heat, and damage normally associated with overtemperature of the particular bearing material.
The usual result of excessive P (still nowhere near the yield stress, mind you) is extreme wear, not necessarily accompanied by plastic distortion.
I am troubled because you appear to be contemplating intentional use of some material beyond its recommended PV value. That's just a waste of money and time.
The recommendations are based on experience. If you do not value experience now, you will, after you have ignored it and then acquired it for yourself.
Mike Halloran
Pembroke Pines, FL, USA