To my knowledge you cannot call a 72.5kV circuit breaker as a "POWER CCT BKR (PCB)" because the word PCB is used for
withdrawble type LV heavy power/sc circuit breakers.
You have to consider both sym & asym ratings of the bkr because,all HV circuit breakers are tested for X/R=17 (Time constant=45ms @60Hz)
means, that it can break an asymmetrical current with max. 67% DC component only. Therefore, the asym current capability =2.6 x sym capability (25x2.6=65kA)
But, if the calculated X/R ratio at the bkr location is higher than 17, then either you have to select a bkr with at least one step higher than 25kA (31.5kA)
or specify a breaker manufactured & tested for special case DC time constant (60ms). Then it will break the sc current at the location comfortably without
violating its TRV capabilities.
Also you can delay the relay operating time slightly so that the bkr will pass the 67% point and break the asym sc current at less than 67%.