My gut response without having a lot of information pertaining to the proposed application, other than it's a structural job, is, it's probably ok. If you're talking about full penetration welds, I'd probably opt for E7018, but, if you're talking about fillet welds in c.s. structural shapes or plate of a relatively light section thickness, I think it should be fine. It's been a lot of years since I used any E7014, and as you may know, it contains some iron powder which increases the deposition rate and also enables the electrode to carry some additional current. As you said the weld surface is typically fairly smooth, and one other characteristic of this electrode is that it can bridge gaps fairly well. As it's classification indicates it's suitable for out of position welding.