Well technically the SCADA is the system, PLCs or DCS' are the hardware platform on which the SCADA system is built. As mentioned by others, history has more to do with it than anything else. PLCs were developed to handle (relatively) high speed discrete digital I/O, high speed counters, timers etc. with the idea of machine control and repeat precision in mind. DCS systems were developed to handle multiple loops of analog control, cascading loops and higher integer intensive math processes, even though reaction speed may be lost because in the process control industry, things rarely happened in fractions of a second. DCS' were also the first to come up with graphical user interfaces.
Now, PLCs are able to handle analog I/O better than they used to, and processor speed has improved to where DCS' can handle higher speed I/O better than they used to. GUI systems as mentioned above, i.e. Intellution, Wonderware etc. eliminated that advantage to DCS systems, but it does still depend on the size of the system, redundancy requirements etc. DCS based systems have a long history of successful operation in very large systems that AFAIK, PLCs with GUIs have not proven yet.
Still, for a lot of applications, the hardware platform makes little difference, other than the familiarity of the users and technicians. For instance, it you have a waste water district that uses PLCs for pump station controls and wants to put together an overall SCADA system to look at their entire district as a whole, it would make sense to use the same PLCs they are currently using as the platform for the SCADA system. On the other hand, if a chemical plant is not using PLCs for anything now, the analog intense application would warrant a DCS as a better solution, and maybe tie in a few PLC-like functions where necessary.
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