Very few measurements are published on dielectrics at those higher frequencies. Not even Rogers corporation will give you data measured on their materials at frequencies above 18 ghz.
You'll probably have to measure them on your own with one of the various resonator techniques (cube, printed circuit, flat sheet). Rogers uses the flat sheet resonance technique.
For information on a large quantity of materials at lower frequencies, I purchased "Dielectric Materials and Applications" by Arthur Von Hippel, from Artech house. It's very old, 1954 vintage but last release date was 1995.
They tested alot of materials up to 10 ghz, and a few to 25 ghz.
kch
(antennas)