Well, it's not quite that straightforward. Your heat transfer path consists of conduction through the steel and calcium silicate, followed by convection from the outer surface of the insulation into the air.
So, you have 3 temperatures to be concerned about, the interior temperature, assumed to be the same as the interior surface temperature of the steel, the external surface temperature of the steel, and tha ambient air temperature. You can model the steel/insulation as a single layer of insulation, by replacing the steel with a thinner layer of insulation that matches the thermal conductivity of the steel layer.
The heat transfer coefficient, you'll just have to dig around on the web. You can calculate it from first principles, using the Reynolds, Nusselt, and Prandtl numbers.
You'll then have two simultaneous equations, with same heat flow in both. The objective is to get a value of external insulation surface temperature that results in the same heat flow in both the conduction and convection equations.
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