The most accurate way is to inspect the CT's, but this can't be done without at least opening the breaker and drawing it out of the cubicle. Unless your're doing this during a normal maintenance outage, that is probably out of the question. With many of the older switchgear designs, the CT's aren't easily accessible even with the breaker out.
If you can locate the drawings, that is a good source - if you have a reasonable degree of confidence that they are up to date. That is a big if, and depends entirely on the diligence of the plant staff. Some are very good, others are very bad.
Many times on older switchgear there are analog ammeters in the same circuit with the relays. The full scale of the ammeter should be equal to the CT primary rating, unless it is some oddball setup. 99% of the time that will give you a valid ratio.
If there have been periodic maintenance tests on the switchgear, they may have done CT ratio checks. If you can locate the test reports, they are a good source of data.
Good luck!