As always when design and safety limits are passed, the question has a safety responsibility side in addition to the purely technical side.
Some additional questions should be asked and answers considered before any decision:
1. If anything unforeseen happens, for instanc to some part of construction or added additional or attached part not taken into consideration, who will pay the damage and bear the responsibility?
2. What person or administrative level has the authority to decide?
3. What is the consequences for yourself?
In this case you are actually asking a question that alters the general view of already set limits. With temperature as the x-axis and pressure at the y-axis your allowable limits describes a rectangle ending (presumably) in a point on the allowable falling pressure/temperature curve(or perhaps somewhat below, safety limits considered).
You ask to extend the rectangle to include the area above the set pressure limit, but below pressure temperature curve.
Por a single item, for a single purpose, this should be OK, if all possible application details and possible accidental occurences are known.
On the other end of the line: for larger projects or aplications consisting of an assemblies or multiple components and a large set of possible risk variables 'someone' usually has put down limits for a purpose.