It depends if you're trying to model surface runoff or infiltration, and under what conditions.
Under ideal conditions, porous pavement will accept (infiltrate) many inches of water. So there may be zero "runoff" in the traditional sense. In this case, you actually need to evaluate the "runoff" that is penetrating through the pavement, and route it through the base layers, and perhaps an underdrain. This can be modeled by using a high CN value (98), together with a long Tc value, to simulate the travel time through the base and underdrain, or perhaps a "pond" to simulate the storage in the stone voids.
In the worst case, the pavement could be fully blocked with ice or debris, in which case you would be modeling normal surface runoff with a standard CN of 98 and a relatively short Tc.
A third option is to calculate an equivalent CN value, based on the potential maximum retention of the base.
Unfortunately, standards for modeling porous pavement are still developing. So your approach will depend on the exact design, and what you and the reviewing agency can agree on. Some states are starting to encourage porous pavement, and are developing standard designs and modeling procedures. As an example, see the work by the UNH Stormwater Center at
Peter Smart
HydroCAD Software