And not just any paint, either.
I remembered a chart I saw some years back. In the Third Edition of the GE SCR MANUAL, 1964, PAGE 280, Section 16.6, Radiation. This has do do with heat sink calculations.
Table 16.3
Material.... Emissivity
Anodized Aluminum.... 0.7-0.9
Commercial Aluminum (polished).... 0.05
Aluminum Paint.... 0.27-0.67
Commercial Copper (polished).... 0.07
Oxidized Copper.... 0.70
Air Drying Enamel (any color).... 0.85-0.91
Oil Paints (any color).... 0.92-0.96
Lampblack in Shellac.... 0.95
Varnish.... 0.89-0.93
"Table 16.3 indicates the wide variation in emissivity for various surface finishes. In free convedtion cooled applications, the radiation component of the total heat transfer is substantial, and it is therefore desiable to maximize radiation heat transfer by painting or anodizing the fin surface"
"Note that oil paints regardless of color improve surface emissivity to practically an ideal value (unity)".
It would appear that the ampacity of a buss bar could be increased by using the proper surface finish. I assume that the "oil paints" are regular oil-based paints.
It might be worth while for new installations to paint the buss bar(s); I will leave that calculation up to you, it's 3:45 AM, the calculation is lengthy and the assumptions are many, and I need some sleep.
I hope this will help.