"you"....yes, damming and flooding is a great curing method, as long as you accommodate the removal of the water and prevent freezing, erosion. It is one method of wet curing.
As for fiber, it has no real impact on curing other than to enhance the crack control a bit in the initial stages. Functionally, it does nothing to the chemical curing process.
a3a...the material you mention is made from either a wax-like petroleum derivative (one form), a polymer, or a combination. These "curing compounds" are intended to prevent evaporation of interstitial water from the slab. They are better than nothing, but do not compare well to wet curing.