Check the CPVC product literature, discuss your question with the manufacturer if his product is certified to serve a hydronic heating system.
From Wikipedia, the melting temperature of CPVC is about 395(not F), and vacate softening point is more than 106C(222F)
in Europe and middle east they widely use nonmetallic piping for hydronic heating systems but I am not sure if CPVC pipe is one of them. If the CPVC expansion is a nightmare, what about cooper pipes or the baseboard itself.?