bencrook:
How big a system you have? What size service transformer(s)?
Are there individual transformer for each building?
You may want to know why was it installed as ungrounded system in first place? What kind of occupancy this buildings have?
Nonetheless, based on what you posted, I do not see any problem with grounding one corner of a delta system. It is not very common, but it is one of the recognized method sof grounding, even by NEC. It is safe.
Be sure to identify and educate the operators and maintenance persons of the same.
There is nothing special to it, you take one the phase at the service entrance equipment and bond it to the grounding electrode/water pipe/ buiding steel etc, as you would with a neutral of a 4 wire system.
Also make sure all of your equipment enclosures are firmly bonded to the ground (not to the grounded phase, except for the service entrance equipment)
If the a common transfomer/service feeds multiple buildings, make sure you ground the same 'phase' at every service entrace.
Ungrounded systems, should have had some kind of ground fault monitoring system, do you have that?