All switches and breakers are "rated", or I should say TESTED, for carrying 100% of their stated capacity. So a 100A switch can carry 100A, a 200A switch can carry 200A, etc. etc.
But if the switch also includes the Over Current Protective Device (OCPD), then you just cannot USE them that way. That's because because the conductors must be sized for 125% of the circuit ampacity anyway, and the purpose of the OCPD is to protect the conductors. So the "80% rating" comes about as the inverse of 125%. Example: I have a load that takes 100A. I must use conductors that are rated 125A minimum. I can use a 125A circuit breaker for those conductors, but I cannot load them beyond 100A. 125A CB, maximum 100A load, so 100/125= 80%
It's a common misconception, fostered by the used of the term "100% rated breaker", which is an entirely confusing issue for most people and cannot be used as often as some people would like, because the conditions of their use are usually well beyond what they understand.
"Will work for (the memory of) salami"