Yes, there is a bond test or pull-off test for concrete coatings.; Check with ASTM - I can't remember the number, it was 25 years ago when I built my first CANDU reactor and we were testing epoxy liners. You coat the concrete sample, score the coating and concrete with a 2" diamond drill bit, glue on a 2" pipe cap, and record the tension required to pull the cap (hopefully with coating) off the concrete.