Hi Don Pepe / choplifter,
helicopter main rotor blade was made from metal (aluminium) as far as i know, because of this the earlier rotor blade need hinge to overcome the coriolious effect. His manufacturing should be similar to other normal metal wing -> bending.
The modern main rotor is made from composite as skin and nomex/honeycomb or hard foam as core, also called sandwich. Because of the flexibility it then doesn't need hinge again, so it is called hingeless main rotor. The manufacturing is the like other composite part :
prepregs -> lay up over the die -> curing
Hope it would help you!
regards