From reading your post, I can see that you take your work seriously and it's always refreshing to see someone who is dedicated to what they do and always wants to learn more. Good for you.
As for concrete, it is a relatively complicated material in some respects and very simple in others. Chemically, it is very complex. While we are still learning about the complex chemisty of cement and concrete, we know enough about the basics of cement and concrete technology that we can predict its performance based on initial characteristics and some basic testing.
As a technician, your job is to observe, test and report....plain and simple. Your task is not to troubleshoot the mix or modify the mix in any way. However, the accuracy of your observations, sampling, testing and reporting will go a long way toward helping others who have the responsibility to correct concrete problems.
The concrete is typically produced by a ready-mix supplier. That supplier has the responsibility to deliver a concrete mix to the jobsite that is within the requirements of the specification. When it arrives to the jobsite, it should not be changed in any way (such as adding water to the mix) except by the ready-mix supplier's quality control person. That is not you, that is not the concrete placement foreman, that is not the project superintendent or anyone else except a quality control employee of the ready-mix supplier. If anyone else changes the mix before it is placed, that person then takes on the responsibility for the performance of that mix.
In order to further understand concrete placement in cold weather, I suggest you obtain and read a copy of ACI 306R "Guide to Cold Weather Concreting". The National Ready Mix Concrete Association (NRMCA)has a guide for cold weather concreting that has some good information, but is certainly not complete in its treatment of the subject. I am attaching a copy of the NRMCA document for your use. I cannot post a copy of ACI 306R as it is copyright protected and sold by ACI.
An excellent book to give you a thorough background in concrete technology is "Properties of Concrete" by A.M. Neville. Any edition will help, but the latest are the 4th and 5th editions.
Good luck and keep knowing that your task is important. Be well informed and learn as much as you can.