Stripping of sulfides is dependent on pH. In treating aulfur waterws, the most important fact is that carbon dioxide comes out of solution much more easily. As the carbon dioxide comes out, the pH rises, in the wrong direction of air stripping. At pH value 5, about 98% of sulfide is present as hydrogen sulfide. On the other hand, at a pH of 9, only one half on one percent is present as hydrogen sulfide.
Regarding: may be the Online oxidation of H2S by injection of air before sand filters not enough and we have to add a chlorine oxidation. what do you think? please
Oxidation by hydrogen sulfide by air is a very slow process and may take hours to complete. That means hydrogen sulfide will not be completely oxidized within the filter retention time.
pH, iron, manganese, and hydrogen sulfide concentrations should be determined in the field since these parameters are not stable.
Water samples must be tested on-site, or immediately stabilized for laboratory analysis. Sample bottles with stabilizing chemicals should be obtained from the laboratory that does the analysis. Careful sampling according to laboratory recommendations is critical to ensure accurate and reliable results. In general, the requirements will involve delivery of a refrigerated sample within 48 hours of collection. Sulfide concentrations are reported by laboratories in units of milligrams per liter (mg/l) or parts per million (ppm).