Actually, it doesn’t take too much review of NFPA 497 Table 4.4.2 to see there are quite a few "maverick" gasses with respect to “Groups” and there isn't necessarily any direct correlation. Group C is the most free-spirited. It is usually Group IIA, but occasionally Group IIB; even a few Group Ds, like Methyl Acetate will wander over to Group IIB. Annex A, Table A 3.3.5.1 explains why this happens – the basic test methods are different and the Minimum Experimental Safe Gap (MESG) values are significantly different.
While it may be customary by some recommended practices, neither classic IEC Zones, nor NEC Zones actually specify a time duration envelope. Careful reading of classic IEC Zones will find them defined in terms of “probability;” whereas, US Divisions and Zones are ultimately defined in terms of “possibility.” Article 505 “force-fit” Zones into the classic Division model. While IEC Zone 0 would always be Division 1, IEC Zone 1 could be either Division 1 or Division 2. Even at the “bottom end” what may have been classified Zone 2 or Division 2 by one system may be “unclassified” by the other.
All that being said Class I, Division 2, Group D is most likely Zone 2, IIA – unless its Methyl Acetate, of course. (Side note: Simply calling it “Zone 2” automatically specifies that it is Class I, “Zone 2x” specifies Classes II & III)