Clark (1945) defined Tc as the time from the end of effective rainfall over the watershed to the inflection point on the recession limb of the surface runoff hydrograph. In practice, for ungaged watersheds this time is usually estimated by empirical equations since runoff hydrographs from the watershed are not often available. See Papadakis and Kazan (1987) for an empirical equation for time of concentration.
Papadakis, C. N., and Kazan M. N., "Time of Concentration in Small Rural Watersheds," Proceedings of the 1987 ASCE Engineering Hydrology Symposium, Williamsburg, Virginia, pp.633-638.