Is anyone checking the pH of the drywall?
It is well known that hydrogen sulfide gas may be produced when landfilling or using gypsum as alternate daily landfill cover, particularly in a wet climate. Several conditions are required, including a moist, anaerobic environment and a low pH. Hydrogen sulfide gas is toxic at high concentrations (~1,000 parts per million) and has a foul, rotten-egg odor.
H2S is a weak acid, donating two hydrogen ions in neutralization reactions, forming HS- and S-2 ions. In water, the three sulfide species, H2S and HS- and S-2 ions, are in dynamic equilibrium with water and H+ and OH- ions. The percent distribution among the three sulfide species depends on pH. H2S is dominant at low pH, the HS- ion is dominant at mid-range pH and S2 ions dominate at high pH. In this equilibrium situation, sulfide ions revert to H2S if the pH falls.
In water, sulfide can exist in three forms; hydrogen sulfide (H2S), bisulfide (HS-), and sulfide S-2. The sulfide species present is dictated by the pH. At pH values less than 6, hydrogen sulfide (H2S) dominates.