The definition of a centroid is 'it is the point about which the first moment of the entity (length, area, volume or mass whichever is relevant to the context) is zero'. Physically, it is the point at which the whole mass (or length, area or volume as the case may be)of the body appears to be concentrated. In other words, it is the point at which the object will balance if supported with a single point support.
In your case, similar to many other shapes like 'L' or other open curves, the centroid or the point at which the body can be balanced with a single support lies outside the body. This is purely due to the shape of the body.
If one needs to support such an object through this point, the object needs to be externally connected to this point suitably before providing such a support. For the other objects with their CG lying inside them, such an arrangement is not needed.