A positive pulse happens from an opening exhaust valve at (say) cylinder 1.
This travels down that exhaust header until it reaches an expansion or a junction (which, to that pressure pulse, is an expansion).
The positive pressure pulse splits at the junction and travels BACK up the adjacent header pipes connected at that junction at the speed of sound and also down the collector and because it was an expansion, it gets reflected as a negative pressure wave back to the cylinder that created the positive pulse a few milliseconds earlier.
If that negative pressure pulse happens at a favorable time in that cylinder's exhaust stroke ... THAT is where the scavenging comes from.
Of course, the positive pressure wave that went back up the adjacent header pipes has to be accounted for, too. Hopefully when that gets to the exhaust valve for that cylinder, that exhaust valve will be closed. But it might not be, because you can't tune these things to work at all possible engine speeds. It could very well happen during THAT cylinder's valve overlap period, thus causing exhaust reversion in that cylinder.
Engines that have overlapping exhaust strokes (counting the whole exhaust valve opening time, not just the "nominal" exhaust stroke!) are prone to reversion caused by adverse pressure pulses. The traditional bent-crankshaft V8 is a disaster in terms of exhaust tuning. Inline-fours with aggressive cam timing can be trouble at low revs (I deal with motorcycle engines ... it's not uncommon to have a trouble spot somewhere near half of rated RPM / two-thirds of peak-power RPM). Inline-threes are pretty good, and sixes with split headers (as on your video) such that it acts like a pair of inline-threes are pretty good - the exhaust strokes are for all practical purposes non-overlapping.