My experience says no, there is no way to accurately pre-determine the differential pressure of a space based on supply and exhaust flows. The reason for this is that all rooms are "leaky", meaning some air leaks out of door jambs, window sills, wall joints, ceiling tile, etc. Also, the reference point for checking the diffential pressure probably fluctuates.
But there are still some basic rules-of-thumb to follow:
1. First, choose a stable reference point to measure your static pressure to. If the reference point is outside, try adding a dampner to it and try to have it equalize for wind loads by tying-in multiple spots around the building. If the reference spot is indoors, keep it away from doors or other spots where the pressure can change easily.
2. Second, if you want a space slightly positive to another space, make sure the supply air flow is greater than the air removed from the space (this includes return and exhaust air). My company usually designs at 0.5 cfm/sq ft of extra supply air to give about 0.04" wg static pressure. Though this is variable based on the "tightness" of the room shell.
3. If you want a space that is slightly negative, make sure the supply air is slightly less than air removed from the space.
4. Ultimately a field balance will set the extra outside air flow or exhaust air flow to obtain the differential pressure your trying to obtain. In order to maintain the pressure you will need an automatic control to measure the pressure and adjust the supply air or exhaust.
5. Finally, items to consider with static pressure are: Will the exit doors still open when the room is positive or negative to adjacent space? Will the room pressure cause moist air to enter wall cavities and cause ice or mold problems?
Good luck.