If cable insulation is sufficient for the voltage of the enclosed conductor to ground, the insulation of two cables will under all conditions be sufficient for the voltage between two phases. Your 480V system, not matter how grounded, will not see significantly more that 480V between conductors regardless of fault type. You can move the whole voltage triangle around relative to ground, and you can collapse the triangle, but you can't materially expand the triangle. Other than an arcing ground fault on an ungrounded (capacitively grounded) system, you can't get to 600V to ground on a 480V system. The arcing ground fault can cause severe overvoltages that are extinguished when something flashes over and no cable system is intended to protect against those overvoltages.
Why do you continue to want to fight years of accepted practice? 600V insulation is suitable for all 480V systems, no further testings/ratings needed.