Check Mark's Handbook, Fittings for steel pipe, page 8-211. Fig 8.7.15
The joint prep is initially cut off square.
The end is beveled 37.5 degrees +-2.5 degrees. The edge is maintained square 1/32-3/32"
If you use the Astro-Arc I mentioned before, you cut off the joints square. there is a fitting that centers, guides, and provides the filler material.