ryanethan;
Portable hardness testing can be used as a process control check, nothing more. If the hardness test results are within an acceptable range for the service duty of the component (or based on client's specification requirements) along with other process checks (review of PWHT temp range and time charts, etc), the hardness would verify PWHT was performed.
Mechnically safe???? You have more than just PWHT requirements and hardness to deal with, you can have NDT requirements, which are equally as important regarding performance of a weld joint in service.
The hardness you mention are acceptable to what I would expect for the given dissimilar weld joint welded with E9018 B3.