I agree with everything said to this point. As with any design change, you need to do a calculation to verify the pipe wall thickness vs the allowable stress, corrosion allowances, mill tolerances, etc.
That being said, if you're using steel piping, chances are sch 40 piping will handle your pressure requirements with a lot to spare. The flange rating is generally the limiting factor in this pressure range.
A heads-up. If this is boiler external piping make sure you get the right pipe - SA-106 gr. B vs A-106 gr. B, etc.
One more thing - why is the pipe wall being questioned in the first place? Did you have a failure of some kind?
Good luck
Greg