The spray water ones I have seen are always taken BEFORE main feedwater isolation valves and control valves, except that you might have s surface (heat-exchanging) type of attemperator.
For the surface type attemperator designs, yes, the take-off points are always located after the control valves. I figure that is because, after going trough the attemperator, the water needs to come back and return to the main feedwater before going to the economizer but since this water has already lost some pressure head by going through the coils inside the attemperator, a throttle valve has to be installed on the main line, which is parallel to the attemerator line, so as to create a pressure drop that is equal to or a bit higher than what the attemperating water has lost thus the two streams can possibly join together. Now imagine, if attemperating water is taken before the feedwater control valve then this control valve will then be in serial with the throttle valve and become another throttle valve. When it tries to change feedwater flow its pressure drop changes this can mess up the pressure balance with the attemperator then messes up the attemperator flow control.
boilerone