Sort of. Some of the time.
Assume you actually have what the climate "scientists" actually assume is a "perfectly clear atmosphere" (no dust, no clouds, very, very low humidity. At high solar elevation angles, you get about 8% diffuse radiation, in addition to the direct radiation. Look at your shadow: It is dark (obviously) but is not "black as night" but the edges are pretty sharp. Still, it would be easy to read a print or small type in the shadow from the diffuse radiation. As the sun gets lower in the sky (dawn or dusk) Soviet diffuse-to-direct radiation ratios measured in the high Arctic on what they called clear days greatly increased as more and more light bounces around before getting to the ground. So, even on clear days, diffuse radiation could be as much as 50% of the direct radiation - in the morning and evening. But, the amount of direct radiation goes down so much compared to the amount at noon that you still really can only use solar power 6 hours a day. 9:00 AM to 3:00 PM local solar time.
Now, take a high, thin cloudy day, completely overcast. Almost no direct radiation, everything is diffuse. Your shadow line is very indistinct. Direct to diffuse ratios don't make much sense, and a double sided receiver might appear logical. BUT! There is little radiation getting through those clouds, so you still are not very efficient even if you gathered energy from both sides of the collector. Neither is getting much energy, but the back side is getting more relative to the front.