Hello all, rconner has already given the correct answer.
Both Kv and Cv values are not unitless factors, but will contrary always require that the units and conditions must be given.
The whole purpose of both Kv and Cv are to give the actual measured flow through a valve at given conditions: pressure loss and type of fluid (water) and temperature held constant, and flow amount (expressed in volumetric units per time unit) given as the measured result.
For normal ball valves, with exact equal opening, the figure will not be very significant different from make to make for new, undamaged valves.
Different actual openings (reduced bore opening in fact where only nominal opening data is given) will of course give the wrong result if you take the nominal opening trying to figure out the flow.
So: check the actual units and conditions standing behind the Cv's you have been given, check that the opening diameters are the real minimum openings, and third ask if the result is measured figures or if the company has given an approximation based on measurements of valves of diameters near, but not equal, to the ones you have.
The comparison can only be made correctly if all these factors are known. It might well be that several of the possible explanations given by others are part of the 'real' answer to your question.