R1chJC,
Yes, it is legitimate, just not necessarily the best dimensioning scheme. Fixturing it to hit your Ø0.1mm positional tolerance will be a challenge. As the designer, I would be looking for a way to open that up.
I am not going to propose a dimensioning scheme because I do not know how your part works. If perpendicularity to the angled face matters, you need to specify a datum, and call it up on the block. You can add a second line to your feature control frame with the additional datum.
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JHG