If you mean you want to put copper and aluminum conductors in parallel on the same portion of a circuit, I don't think this is a good idea.
When cables of similar material are connected in parallel, the assumption is that the current will be equally divided among all the conductors because each segment has approximately the same impedance. If you use differing materials and/or sizes, this is no longer the case and I would be concerned that the current will divide unequally and you cannot be sure that one segment will not become overloaded.
This is NOT allowed by the National Electrical Code in the US, and I suspect this is the reason.
It would interesting to do some calculations....