1. What is the design code that you are required to work to - is it B31.3? Assuming yes (which is not necessarily the case since you indicate this is at a gas injection wellhead), you would look at Table 326.1 to determine the listed component standards. Something is either on that list or not. If it is on the list then liability for acceptability of design and materials is substantially reduced as the component is "pre-approved". If it is not on the list then the "designer" is responsible to ensure that the component meets all the requirements of B31.3 (see Clause 326.1.2 and 326.2.2). In this case, API 594 is a listed valve standard so you don't need to worry about this issue.
2. It is very difficult if not impossible to provide a comprehensive set of rules regarding what substitutions may or may not be acceptable. This will be highly dependent on the specific circumstances of each job. Some of the more important things you have to consider are:
- Do the materials have equivalent low and high temperature ratings (impact test values for example)
- Do the materials have similar mechanical properties such that they have the same pressure ratings
- What are the possible considerations with regards to the service environment (e.g., susceptibility to problems in H2S service)
- Are the materials of the same type (e.g., forgings, castings). Some clients will not accept castings in place of forgings unless they receive supplemental examination.
- Do the materials have similar weldability
Note: one common mistake I've seen people make is to accept SS valves as a substitute for CS not realizing that SS flanges have lower pressure ratings than CS flanges and so they then should be derating the entire piping system and resetting their PSV's.
3) that depends on the client and the clients specs. Somewhat addressed by my point 1 above. If the client specified B16.34 then it is a contractual problem and the client may reject a valve that does not comply. It is common for B16.34 to be specified but it is also extremely common for API 594 to be specified. One possible issue is that B16.34 specifies the required wall thickness of the valve body but API 594 does not. This means that a valve purchased to B16.34 is assured of meeting a minimum standard. A valve made out of A487 material to API 594 is subject to the discretion of the manufacturer and so depending on whether the manufacturer is trying to save money, may have a less robust design - there is no specified minimum design wall thickness.
4) It is not clear that you can positively state that A487 Gr 4C is an acceptable alternative to A216 WCB. They are different materials and there may be some technical reason that the client has (that neither of us is aware of) that makes the A487 material unacceptable to him and to be honest, while it might be nice if he did, he is under no obligation to justify his rejection of a material that does not meet the contracted specifications. Myself, I'm not intimately familiar with the properties of A487 (nor do I have any detailed information on the service) and so without comparing the A487 and A216 standards side by side can't positively comment on whether A487 is an entirely acceptable substitute. There may be differences in heat treatment requirements, in examination and inspection requirements, etc.
The Client may reject your waiver on non-technical basis as well. I've been on the client side many times and on a large project you are inundated with so many requests for deviations and exceptions to project specifications that you simply cannot respond to every one. I've often been forced into the situation (purely on the basis of time management) of refusing to review deviation requests unless the person putting forth the request can demonstrate that the original technical requirement could not practically be complied with.
Another possible reason for rejection is that the client representative simply does not have the technical expertise to evaluate the proposed recommendation and it may cost him/her money to get impartial third party advice. Since they have a contract in place that specifies a technically acceptable product, which is available, they may not see why they need to spend time and money evaluating alternatives.