< at which point the flow does not increase further when pressure is increased. >
No. If you have a fixed pressure and drop the outlet pressure and get choked flow, future reductions in the downstream pressure does not increase the flow.
However, if you start at a higher pressure, when you choke the flow through the orifice will be higher than in the case of the flow of a lower, but still choked, pressure.
< Is there and mathematical formula or chart that you know of, to see the difference in flow rate between the 2 pressures? >
For both 40 psig and 80 psig flow to the atmosphere, you will get choked flow. As a rough guide, a pressure drop of 1/2 the initial absolute pressure (psia which equals psig + atmospheric pressure) will be getting you close to choked flow.
The ratio of the two pressures in psia will give you a reasonable estimate of the two flow rates, assuming the pressures aren't high enough to start to affect parameters like compressibility which won't be the case for these pressures.
(80 + 14.7) / (40 + 14.7) = 1.73 The orifice with 80 psig inlet pressure will flow about 1.73 times the 40 psig case.
< s the 80psi system going to deplete at say 5psi/second where as the 40psi system depletes at 2psi/second?? ----is there any way to find out the rates of depletion of each system? >
Depends on the size of the orifice and the volume of the system.