Maintaining the same V/Hz ratio maintains the same FLT of the motor That's what a VFD does at it's basic level. Without Vector Control, you can alter the V'Hz ratio to gain additional torque, but it also increases the flux, which unnecessarily heats the motor.
Vector Control, through complex manipulation of controllable variables, provides the ability to "tweak" the output in such a way so as to increase the output torque up to and including the Break Down Torque*, which is the PEAK torque the motor is capable of, at any time; temporarily. In a way, the "tweaking" is akin to changing the V/Hz ratio, but it is way more complicated than that. However the effect is similar in that it is not something that can be sustained indefinitely without deleterious effects on the motor and/or drive.
On a common Design B motor, Break Down Torque is generally higher than Locked Rotor Torque. LRT = 150-160% of FLT, BDT = 200-220% of FLT. So if you were wondering if a Vector Drive can accelerate a motor faster than an Across-the-Line starter, the answer is yes, provided the load can be accelerated within the time the motor and drive can tolerate the effects of an increased output.
"Will work for (the memory of) salami"