Thublena...
I was privileged to take a 5-day corrosion course from the premier Army corrosion engineer, LLoyd O Gilbert, back in the 1986 time frame.
Eventually I discovered the corrosion course notes [binder full] were essentially transformed into MIL-HDBK-735 MATERIAL DETERIORATION PREVENTION AND CONTROL GUIDE FOR ARMY MATERIEL, PART ONE, METALS.
The presenter had a specific example of a M-16 forged/machined receiver, 7075-T6 black anodized, that had developed massive EXCO due to perspiration from a sweaty hand during actual SEA combat operations. He had an actual M-16 receiver as part of the course show-n-tell... absolutely amazing damage matching where finger of troops normally gripped the receiver... and was similar to what we were seeing on older Acft parts [-T6 temper] in a sea-coast environment.
During his discussion I am, certain he stated that the soultion to this problem was heat treating the die forged receiver to -T73 [EXCO & SCC resistant], instead of -T6 [EXCO & SCC prone]... then black anodizing and application of a baked-on SFL. For some reason, I don't remember shot-peenining... which I now know to be an excellent way to retatrd SCC & EXCO initiation... I think because of the complexity the interior cavities of the M-16 machined reciever.
Here is the extract from MIL-HDBK-735 RE M-16 corrosion.
4-2.4.2 Exfoliation
After a [M-16] rifle had been in service for 3 yr in a hot and
humid climate (Southeast Asia), exfoliation corrosion
was detected on parts of the lower receiver (Ref. 33). The
part affected had been protected with an anodic coating,
but the affected areas were those frequently in contact
with the hands of the soldiers and thus were exposed to
the chloride ion in perspiration. The original specification
required a minimum yield strength for the aluminum
forging of 448 MPa (65 ksi). The manufacturers supplied .
alIoy 7075 in the T6 temper, which did have adequate
strength.
An investigation was conducted on alternative tempers
of alloy 7075 that might have adequate strength and
greater exfoliation resistance than the T6 temper. Newer
a310ys with adequate strength and greater resistance to
exfoliation were also investigated.
Some conclusions of the investigation are
1. Alloy 7075 die forgings can be thermally treated to
produce an exfoliation-resistant material with a minimum
yield strength of 448 MPa (65 ksi). a
2. In the T6 temper, 7075 forgings exhibiting a
randomized grain structure, as found in those produced
from rolled bar stock, are more resistant to exfoliation
corrosion.
3. Other 7XXX series alloys, such as X7050 and
premium grade 7175, can be thermally treated to produce
a variety of exfoliation-resistant forgings with much
higher strength than 7075.
4. Temperature and length of aging are very
important factors to control to insure that the optimum
combination of strength and exfoliation corrosion
resistance is obtained.
NOTE.
During an investigation of an OV-10A that developed an unusual/sudden problem of the main landing gear hanging up during retraction and extension. We discovered that a hot-air leak from a poorly installed "S-exhaust duct" was directed against a large area of the machined frame containing the MLG trunnion. This leak severely damage the epoxy primer [classic sign of over-heating]. We identified a technical study where 7075-T73 was exposed to hot conditions exceeding aging-bake temperatures [like exhaust leak]. The report concluded that the material would distort [grow] substantially due to over-heating effects... which accounted for the sudden binding of the MLG due to Trunnion bearing misalignment cause by permanent material distortion.
In truth I believe that a new generation 2xxx series alloy would be a much better choice. Even old standbys, such as 2219-T852 or a 2124-T852, would work better. These 2xxx-T8 alloys/tempers have good EXCO/SCC resistance, good strength, good fracture toughness and outstanding long-term heat exposure resistance.
NOTE, RE M4.
I understand that the SEALs discovered that the M4 was prone to failure during extended/intense combat operations, due to over-heating of the receiver, bolt and/or gas-operating parts... and possible gun-gas-residue accumulation. This phenomena was discovered during unexpectedly long combat engagements, when a few hundred shots were fired through these weapons in almost non-stop action. This went against the grain of SEAL training where brief/intense engagements were the expected NORM... not prolonged engagements which they have actually experienced. Needless to say this has caught the SEALS attention in a very negative way.
Regards, Wil Taylor
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