For me, there are 2 concerns. First is "code compliance" and second is "are these flanges safe?" In my previous life (30+ years with "Big Oil"), it was recognized almost 40 years ago, A105 flanges were a problem in low temperature service and most bigger companies with lots of tech resources and $$ moved to A333 piping and A350 flanges. My current company does PHAs and in my experience, lots of smaller companies are still using A105 flanges in new construction in spite of the knowledge that A350 would be better and not much more $$. ASME didn't change the MDMT curve for A105 flanges for no reason which raises the question "are these A105 flanges safe at 0 deg F". I can deal with the "built to an older code" problem, but I don't know how to give assurance that the existing A105s are safe. The link that "Some Curious Guy" sent above wrt Mn content may be useful. If the flanges in question are "as forged" not A105N, can I give some assurance they are safe with PMI testing assuming a certain Mn content? Thanks for all the comments... greatly appreciated.