Voltage ratio between primary and secondary (at power system frequencies) is only a function of the ratio of the number of windings. For a given kVA rating a 50Hz core (transformer or motor) will be larger than a 60Hz core. Voltage ratings still apply and since many 50Hz voltages are somewhat less than the 60Hz equivalent (400V vs. 480V, 11kV vs. 13kV, 400kV vs. 500kV, etc.) you may find you have voltage rating issues trying to use a 50Hz transformer for 60Hz applications but the core won't saturate.